PPC (PowerPC) is the processor architecture of all G3, G4 and G5 Power Mac computers.
PPC Macs cannot run any OS greater than Leopard, 10.5.8 because after that, Apple quit developing for PPC processors and limited support for the Intel processor line only.
As for upgrade to Leopard, Yes, if your machine meets the minimum requirements of 867 MHz or faster processor, 512 MB or greater of RAM and has a DVD reader it can have Leopard installed.
To install Leopard, one must first purchase a RETAIL (black with X on it) disc.
After install of 10.5, 10.5.1,10.5.4 or 10.5.6 retail version, free updates to 10.5.8 are available from Apple.
Check eBay for discs:
http://www.ebay.com/sch/i.html?_nkw=mac+os+x+leopard+retail+10.5
If your machine is slower than 867 MHz, Google "Unsupported Leopard Installation".
Tiger is lthe best choice for slower PPC Macs.