Q: First Song in Baker Street Missing After Sync

Hi XIIIV,

If you're unable to get a particular song to sync via automatic syncing with iTunes, it may help to try enabling 'Manually manage music and videos' for your iPhone, then try dragging the affected song to your device.

Move content from iTunes on your computer to your iPhone, iPad, or iPod touch
https://support.apple.com/en-us/HT201593

All my best.