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Sep 27, 2016 3:01 PM in response to petric83by Kenichi Watanabe,You'll need to use a third-party method or utilities. iTunes syncing is generally in one direction only, from iTunes library to iPod. An Internet search on something like "ipod podcast transfer" may provide some options.
Also, if this podcast was downloaded through iTunes, you should check the Podcasts section of iTunes Store to see if that particular podcast is still available for download. Podcasts are free, so if you find it, just download it again instead of scavenging files from your iPod.