But I can say for sure that you can copy a non-mirror to a mirrored set with CCC.
CCC is just a series of scripts that copies data (using ditto) from one volume to another. It's just copying data, it's not modifying partitions.
I don't have an answer as to why it's not working for you. It should.
And considering you can successfully clone to a single drive which boots, I won't get into the basics of CCC (like the Bootable checkbox).
Jeff