Was going to pass, but:
There is some OS and other files on the iPod, but they aren't near that large.
The difference you are seeing is due to a difference of how the disk manufacturer measures the drive and the way the computer sees it.
Read this article from Wikipedia:
"Some operating-system tools report capacity using the same abbreviations but actually use binary prefixes. For instance, the prefix mega-, which normally means 106 (1,000,000), in the context of data storage can mean 220 (1,048,576), which is nearly 5% more. Similar usage has been applied to prefixes of greater magnitude. This results in a discrepancy between the disk manufacturer's stated capacity and the apparent capacity of the drive when examined through some operating-system tools. The difference becomes with 7% even more noticeable for a gigabyte. For example, Microsoft Windows reports disk capacity both in decimal-based units to 12 or more significant digits and with binary-based units to three significant digits. Thus a disk specified by a disk manufacturer as a 30 GB disk might have its capacity reported by Windows 2000 both as "30,065,098,568 bytes" and "28.0 GB". The disk manufacturer used the SI definition of "giga", 109 to arrive at 30 GB; however, because the utilities provided by Windows define a gigabyte as 1,073,741,824 bytes (230 bytes, often referred to as a gibibyte, or GiB), the operating system reports capacity of the disk drive as (only) 28.0 GB."
