QuickTime nor any other FREE Apple software will do the job?
Quicktime comes in two flavors, Quicktime and Quicktime Pro. QT is what your computer uses to play things and is free. QTP (payware) unlocks features of QT that lets you do editing and conversion. However, I am not sure that even QTP goes to extent of working with DVD files since Apple has iDVD (more payware) for doing that. I can't answer that since I don't have new QTP and only have a very, very early version of it that dates from early OS8 years which was pretty much pre-DVD!
We can recommend third party software to the extent that is adds to the functionality and use of your computer, we just aren't supposed to provide specific detailed help on these forums on the non-Apple/Mac aspects of third party program usage; e.g., a long detailed description of how to use FFMEG. I'm pretty sure there are FFMEPG forums for that (looks on ffmpeg's website), and if you spend some time with the program you'll find the menu items that relate to my previous suggestions. The hardest thing I found was installing ffmpeg because you have to do it in several steps, but it is free and will do what you want. 'nuff said 😉