1. Can you daisy-chain four relay stations between the main and a single remote to get a super long distance?
Sure but your bandwidth would suffer greatly. Every WDS link cuts the bandwidth in half. With your proposed configuration, you would have 5 WDS links which would mean that you bandwidth would be
1/(2**5) = 54/32 of your current bandwidth. In a perfect (laboratory) environment, the resulting bandwidth would be:
54/(2**5) = 54/32 = 1.6875 Mbps