Courtnie, there are circumstances under which FireWire is clearly superior to USB 2 but for iPod use, FireWire won't be that much faster for most of us. Unless you have several fast devices connected to a single USB port or intend to frequently transfer large files to the iPod, don't spend the money to get a FireWire cable.
BTW, I base this advice on real world experimentation. Members of our user group argued fiercely about this after Apple stopped shipping the iPod with a FireWire cable. So I went home and used my G5 desktop to sync my 4th generation iPod using both FireWire and USB 2. I performed a complete 10 gig replacement and then several updates involving several CDs being added and removed. Performing the 10 gig sync FireWire was about 2 minutes faster. Performing the small 200-300 mg updates the difference was basically unmeasurable.
Further testing showed that FireWire was generally faster performing sustained file transfers which would give it the edge with very large files. And given the difference between FireWire and USB specs, FireWire behaves more intelligently when several devices are connected to in one chain.