Assuming your list is in column B, then in a cell in another column, enter this formula:
=IFERROR(VLOOKUP(INDEX(B,COUNTA(B)+ROW(B)-1),OFFSET(INDIRECT(ADDRESS(ROW(B),COLU MN(B))),0,0,COUNTA(B)-1),1,FALSE),"No Duplicate")
This formula alerts you if the last item in the list was already entered. Note, it only checks the last item in the list, so if the list has 10 entries and 2 and 3 are duplicates, this formula will not alert you.
I also added a Conditional Format to make it more apparent when the value of the formula cell changed.
I didn't know how many header rows you had, so this formula is slightly more complicated to account for any number of header rows. If this formula doesn't help, just post more info. I'm sure someone can help.
Robin