There should be an earlier document out there for enterprise deployment. There is a whole section devoted to iPhone enterprise deployment:
http://www.apple.com/support/iphone/enterprise/
The touch, at least for Wifi, is the same as the iPhone.
When you upgrade to 3.0, you will not lose any of your network settings. Although a number of people have noticed flakey network connections after the upgrade. However, I noticed that if I did a reset network connections and logged back in using "Other network", the problems vanished.