Are you trying to make a one-to-one copy of the actual DVD disk? If Toast won't do that then there is something wrong on the disk.
Or are you trying to burn an extra copy from the disk image?
Have you tried using Disk Utility?
To create an image file, launch Disk Utility and select File: New: Disk Image From Folder. In the window that appears, navigate to the desired folder and then click on Image. Give the image file a name, and click on Save when prompted. That’s it.
How to copy previously-burned DVD-R video discs
http://support.apple.com/kb/HT2059