As everyone has mentioned, use Photoshop or any other graphics program. Aperture is a photo developing program. The reason the editing tools are called "adjustments" is because almost all of them operate on the values in the existing pixels -- they adjust those values.
If your sky is totally white (blown-out, overexposed) then the luminosity of all of those pixels is maxed out. No matter what the Hue or the Saturation, with a maxed out luminosity the color will be rendered as white (a really really really really really maximally light version of any color is, by definition, white). So you need to either replace those pixel values -- which is what editing programs such as Photoshop do -- or find tools in Aperture which will lower the luminosity (and perhaps change the hue), which is what some other respondents have suggested.
You will almost certainly be better served by doing this in Photoshop.