Recommended Post Installation Configuration for a 2006 MacBook regardless of the Desktop Enviorment selected during the install.
All of these instructions will be entered on the command line so open up a terminal once you log into the Debian desktop. It is much easier to post actual commands than trying to instruct someone using a GUI interface. Don't be afraid of the command line. A user only needs to become familiar with a few basic commands.
You can become more familiar with the Debian specific concepts and best administrative practices by referencing the information included in the links here. There is a ton of information in those links, so just read or skim for the most relevant topics just to get a basic understanding. I will only present the required post installation steps which I think are relevant. You can use the linked documentation to get a better understanding of the commands I am providing here.
1) Enable the Contrib and Non-Free repositories (needed for WiFi drivers)
You will use the command line text editor "nano" to edit a configuration file to enable the extra repositories so that you can access the WiFi drivers.
sudo nano /etc/apt/sources.list
You are going to edit four lines which begin with "deb" and "deb-src". At the end of each of these four lines add a space followed by the following "contrib non-free" so the end of each line appears like:
main contrib non-free
The actual lines will look something like the following, but the URLs may be different depending on your region:
# deb cdrom:[Debian GNU/Linux buster-DI-rc1 _Buster_ - Official RC i386 NETINST 20190411-23:13]/ buster main
deb http://deb.debian.org/debian/ buster main contrib non-free
deb-src http://deb.debian.org/debian/ buster main contrib non-free
deb http://security.debian.org/debian-security buster/updates main contrib non-free
deb-src http://security.debian.org/debian-security buster/updates main contrib non-free
Once the modifications have been made, press Ctrl + X, then press "Y" to confirm the changes, then press "Return" to save the file and exit the nano text editor.
Now you must update the list of available packages since you just modified the repositories where all the Debian software is located. You must do this whenever you make changes to the repositories and before installing or updating any software so you always have the latest list and versions.
sudo apt update
2) The default command line utility for managing software on Debian is "apt". I personally prefer using "aptitude" to manage installing/updating/removing software instead of the default "apt" utility. If you run "aptitude" without any options, then it will launch an ncurses GUI interface.
sudo apt install aptitude
3) Install WiFi drivers:
There are two WiFi drivers one of which is open source with partial support for the Broadcom BCM4321 chip included on the 2006 MacBook. The other one is an older proprietary Broadcom driver. The open source driver worked well for me and I would suggest trying it first. (If you did not install "aptitude", then use "apt" instead for the following commands.)
sudo aptitude install firmware-b43-installer
If you have problems with the open source WiFi driver, then use the following two commands to remove the open source driver and install the proprietary Broadcom driver.
sudo aptitude purge firmware-b43-installer
sudo aptitude install broadcom-sta-source
Make sure to reboot the computer so it will load the new driver. An network icon should appear either on the menu bar or on the Taskbar depending on the Desktop Environment you chose during the install.