We have thick plaster and wire mesh walls
This is unfortunately a worst case scenario in most homes for wireless connections, as you already know.
need to boost the signal.
If you plan to connect another AirPort Extreme using a wireless connection back to the "main" AirPort Extreme, the AirPort will not really "boost" the signal at all. It will "repeat" the signal, meaning that it can only repeat the quality and speed of signal that it receives.
But chances are, the WiFi signal will have already slowed down and weakened significantly by the time that it reaches the location of the repeater. So not much will be gained by adding the repeater.
For that reason, it is easy to see why you would want to avoid trying to use wireless to connect the repeater if at all possible.
If you can use an Ethernet cable to connect the remote AirPort back to the main AirPort, the remote AirPort will receive a full speed signal to broadcast, resulting in a much stronger and faster WiFi signal for that area of the house.