iPhone XR compatibility to VOLTE
Whether iPhone XR is not Supporting VOLTE?
iPhone XR, iOS 13
Whether iPhone XR is not Supporting VOLTE?
iPhone XR, iOS 13
About the LTE options on your iPhone
The cellular-data options on your iPhone might vary based on your carrier's network.

If your carrier supports VoLTE
On your iPhone, go to Settings > Cellular > Cellular Data Options and tap Enable LTE or Settings > Mobile Data and tap Enable LTE. If your carrier supports Voice over LTE (VoLTE), you'll see these options:
iPhone XR compatibility to VOLTE