Using Preview, you can take a copy of an existing image (any image) or a screenshot of anything.
Resize the image to the dimensions you want.
Select everything in the image (Preview -> Edit -> Select all), and use Preview -> Edit -> Cut to eliminate the original stuff you do not want.
You now have a blank canvas the size you want.
Have Preview open your desired image, and Preview -> Edit -> Select all.
Preview -> Edit -> Copy
Now paste your desired image into your blank canvas.
You should be able to drag the pasted image around to center it the way you want.
If you have created your blank canvas larger than originally desired, you can select what you want to keep, and crop the image to the desired size.