Hi there pdaviesoz,
Thank you for choosing Apple Support Communities!
It sounds as though you’re seeing that a Photos Library stored on an external hard drive is not able to open. You’re in the right place, we’d be glad to assist in seeking a solution.
Below is a resource that can help:
Get help with the Photos app on your Mac
We’d advise trying the steps in the “If you're having other issues with Photos” section.
If Photos can open successfully with a new library, try opening your Photos Library in another user account on your Mac:
How to test an issue in another user account on your Mac
If the Photos Library can open successfully in a new user, try using these steps on your Main Photos Library:
How to use the Photos library repair tool
We hope this helps,
Cheers!