You want High Sierra, if your Mac can get there.
The oldest macOS will Microsoft Office support is now Catalina, for instance.
Performance-wise, I haven’t noticed an appreciable difference between El Capitan, Sierra, and High Sierra. Or with Mojave, for that matter.
Catalina, Big Sur, and Monterey have all made more significant demands of the hardware, so those did get slower on older low-spec hardware. Catalina and later particularly don’t run well on configurations with eight gigabytes of memory and a hard disk drive, or eight gigabytes and a Fusion drive. More memory somewhat masks the slower HDD. On systems with SSDs, those versions do better, even with eight GB.