Hi James,
Unfortunately there is no easy answer on when to use Round or how many decimals you should use.
Every case is different and sometimes you have to make a compromise.
Yes Excel has the identical functionality as Numbers. But there is one exception.
Excel has 3 round functions.

Numbers has also these 3 round functions, plus a special addition "MRound".

Here a comparison of the different functions.
Round, RoundUp & RoundDown was set to 0 decimals / MRound was set to 0.25

Unfortunately it is not easy to say when / how you should use round
I modified your example to show it. Average Cost was changed!

The exact number for Break-Even Qty. would be 100,512.4162
If you use normal round it would round down, because it ends in .4162
But 100,512 units would be not sufficient to reach Break-Even Qty., because the value must be above 100,512.4162
In this case you should use RoundUP, that will always give you the next full number.
You can include your calculation in the round functions, see last row of this table.
I always use 2 decimals for regular tables, if the unit is currency.
For the rest I pick something that shows what I need to know.
I only use round if I really have to, like if I have to create an expense sheet.
Here an example that shows that round can be tricky:
3 People will spent exact $100.00 in a restaurant (including tip), therefore each has to pay $33.33 (when you use round to 2 decimals)!
Unfortunately 3 times $33.33 is not $100.00 ;-(
Ralf