That's never going to work.
First of all, you almost certainly have nowhere near 60 GB of free space. People often get confused by the operating system's terminology of "free" and "available" storage space. Anywhere you see the word "available" being used, simply disregard that completely. It's totally wrong. There are only a few places that will tell you the actual amount of "free" storage you have. The easiest place to find this information is Disk Utility.
Now, your next problem is trying to move data from "iCloud + local" to the external storage. You can't do both. You can move any local files to external storage. Once you free up enough space on your hard drive, then you can start working on iCloud data. But first, you will need massive amounts of truly free storage to begin.
Before you can copy any data from iCloud to your external, you have to download the data from iCloud to your boot drive. That is actually going to consume storage, not free it. Then, when you move it to external, you'll have to wait the 24 hours again before you have more free storage to work with. And keep in mind that you don't actually have 60 GB of storage free. You likely have 5 GB or less. Ergo, this plan is never going to work.
My recommendation is to simply review your total storage use and needs across all platforms. What do you need constant access to at all times? What can sit in iCloud until you need it? What can sit on some external storage. Don't forget about backups and archives. iCloud is not a backup. Time Machine is not an archive. If you are moving storage onto a single external drive, that drive could fail and then your data is gone. Remember that iCloud is synced storage. You can't use it until it is downloaded to your hard drive.
If you need to regularly move 800 GB of data, then your storage needs are likely in the 10+ terabyte range and you will need multiple drives of that size.