my new iphone 14 pro mac is has copied everything over but i cant call on it. my old phone still rings

See the "Transfer a physical SIM or eSIM on your previous iPhone to an eSIM on your new iPhone after setup

" on the following support document for steps you can follow: click here ➡️ About eSIM on iPhone - Apple Support

Did you move the SIM card or eSIM to the new iPhone?

Contact Verizon about that.