Can I use a over the ear headphone for live listen for better hearing

To use Live Listen with your AirPods, AirPods Pro, AirPods Max, Powerbeats Pro, or Beats Fit Pro

Use Live Listen with AirPods or Beats - Apple Support

Those are the only supported headphones

Dasarathi Said:

"Can I use over the ear headphones for better listening with iPhone"

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Using Over-the-Ear Headphones:

Yes. If no microphone, then you might not get sound input. Skullcandy as does Beats.