Hi geode21,
welcome to the Apple (user-to-user) Community.
Re: "Trusted Device list not available when on wifi
"When I sign in on my 5G/LTE, everything is fine. What is causing this?"
"It does not matter what device I use, it does the same thing"
Wondering if all your devices have up-to-date software versions,
eg: About iOS 16 Updates - Apple Support says iOS 16.5 is the latest
and
whether you have signed in (to each device) ok with your Apple ID:
Sign in with your Apple ID - Apple Support
You may need to ensure you are allowing access:
Eg: Third-party (non-Apple), apps, especially ad-blockers, un-necessary virus checkers, etc., even VPN, can sometimes interfere.
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Re: "I get a 503 error. I called apple and they had no idea".
Wondering which browser you use for wi-fi.
Seems this http error indicates that something has stopped your browser from accessing the server ... eg: maybe an outage, or the server was temporarily unavailable. (maybe there's a privacy setting / firewall / stopping your browser)
... or maybe a different browser would have access.
Eg: If Safari doesn't open a page or work as expected on your Mac - Apple Support
and
If Safari isn't loading websites or quits on your iPhone, iPad or iPod touch – Apple Support
All the best :-)