1) Well, in spite of reputation, your Samsung SSD is putting on a command performance:
Performance:
System Load: 1.78 (1 min ago) 2.03 (5 min ago) 2.53 (15 min ago)
Nominal I/O usage: 2.57 MB/s
File system: 14.52 seconds
Write speed: 2982 MB/s
Read speed: 3161 MB/s
Those read/write scores are a faster than my 2017 iMac with a factory 1TB SSD and no Fusion components. Those scores do not indicate that the drive is the cause of your slow booting.
2) I see AppCleaner. "Cleaning" apps are more likely to cause slow boot issues than an SSD running at 3000 MB/sec. Cleaners interfere with elegant, automated self-maintenance routines you paid Apple to build into macOS. Remove any cleaning apps using the developers' removal instructions.
3) This is a known performance killer:
2023-08-17 09:09:59 photoanalysisd High CPU Use
That is a hungry sub-process of the Photos apps and, fortunately, can be dealt with. Please see this article on the subject:
https://apple.stackexchange.com/questions/310594/what-is-photoanalysisd-and-why-is-it-using-77-of-my-cpu
4) I cannot help thinking that a slow boot could be the computer seeing the old mech drive as the boot partition, although the report appears to show the SSD as the boot volume Still might be worth doing System Prefs > Startup Disk to verify the SSD is boot.
5) This can be mitigated in seconds:
2023-08-17 17:13:19 mdsync High CPU Use (5 times)
Processes starting with "md" are related to Spotlight indexing. You can use Spotlight's system preferences to reduce the types of items that your do not think you need to search, or where an app'ss internal search works just as well, like in Mail:

By default, everything is selected. That can be narrowed down to improve performance.
6) As for reputation:
memory upgraded from 8GB to 24 GB now(add 2 8GB kingston memory)
Kingston has been an issue since Macs went to Intel processors in 2006. Like Corsair, they have two tiers of RAM. The upper tier is usually okay in Macs but the lower tier is historically troublesome. The problem is that, the RAM business being incredibly price-sensitive, resellers tend NOT to stock the more-expensive and Mac-friendly RAM versions of either brand. I use only Crucial or OWC RAM and never and an issue.
See if the boot issue changes if your remove the Kingston modulesand test with only the original factory modules in place.