The Photos app is in the Applications folder, and it's usually available in the Dock and in the Launchpad.
The Library that has your pictures and data, by default named "Photos Library.photoslibrary," is usually located in the Pictures folder, but it can be moved.
You can do a Finder search for anything with the extension ".photoslibrary" like this:

so if you select the Library in the window, it's path will be shown below.
Be sure to look into Trash and iCloud Drive. It can't work in either of those places, and sometimes the get accidentally dragged along there, somehow. If you find it there drag it back to the Pictures folder.
You can also close Photos and then option click on the Photos icon to bring up a dialog that shows the Libraries that Photos knows about--

but Photos has already said it can't find yours, so this probably won't help.
Are you using an external drive? If so, look there, too.
Let us know what you find or if you still can't locate it.