FYI, there is no need to run MalwareBytes 24/7. There is an option within the MalwareBytes to turn off real time scanning (it is a paid feature that is enabled during the free trial period of the extra MalwareByte features). The real time scanning is what can cause all sorts of system stability & performance issues. The free version of MalwareBytes is all that is ever needed....run it & update it when you suspect you may have malware or adware.
Now for an explanation of macOS storage....Apple makes storage much more confusing than it needs to be. You mentioned in your initial post that you were at a critical 97.24GB of storage. The EtreCheck report you posted shows you actually only have 25.30GB of Free storage space that can be used immediately. The other 75GB is currently not accessible for you to use right now.
So why is there such a discrepancy? Look at the EtreCheck report here:
disk3s5 - Data [APFS Virtual drive]
Filesystem: APFS
Mount point: /System/Volumes/Data
Encrypted
Used: 434.30 GB
Shared values
Size: 494.38 GB
Free: 25.30 GB
Available: 99.23 GB
See the Free and Available storage values listed at the bottom of that section? That is the problem. Unfortunately Apple only shows the very misleading "Available" storage value everywhere within macOS. The only places Apple shows the Free storage space value is within Disk Utility or the Apple System Profiler (aka System Information). This is very unfortunate since the Free space value is the most important & critical storage value in macOS.
Free space is storage that you can use immediately. Users should always have at least 20GB+ of Free space at all times. Even that 20GB of storage can disappear very quickly even with light system use. Ideally people should have at least 20%+ Free storage at all times. With some workloads you may need even more Free space (video editing is one such case).
Available space is storage that at some point will be released & made available to the system for other purposes at some unknown time in the future. Available storage consists of both Free space and also Purgeable space. The Purgeable space is what will be released at some unknown time in the future. Sometimes you may see Apple show Available space and also show Purgeable space in parentheses like so you can actually calculate the actual Free storage space:
Available: 99GB (74GB purgeable)
Free space = Available space - Purgeable space
Available space = Free space + Purgeable space
Purgeable space = Available space - Free space
Using the information from the EtreCheck report:
Purgeable space = 99GB Available space - 25GB Free space = 74GB Purgeable
25GB Free space = 99GB Available space - 74GB Purgeable space
Even the Used space value is not always what it seems. There are circumstances where you may see your system using more storage than the size of the physical drive itself. That is a tale for another day.
TLDR: The Free storage space value is the most critical storage value you need to worry about. Never let it go below 20GB for any reason. It is best to keep the Free storage space at 20%+ of the size of the drive. The Free space value is most easily seen in Disk Utility. Completely ignore the Available storage value since it is so misleading. Bad things can happen if you completely run out of Free storage space including not being able to delete any files from an APFS volume, so a complete erase, reinstall & restore of data from a backup is required. With a MacOS Extended file system, silent file & data corruption can occur.
Concentrate of fixing the system first, then take time to re-read this post to familiarize yourself with the macOS storage terminology.
FYI, when you delete data, you may not see any change in the Free space for a day or two due to how macOS works especially when using Time Machine backups or even third party backup software (the Available value will increase which we now know should be ignored knowing it should lower in a day or two). Data you delete today will still reside in the backup APFS snapshots until they are automatically deleted by the system or the backup software (TM or third party). The EtreCheck report shows you currently only have a single TM backup snapshot on your system so in about 24-48 hours that snapshot will be deleted & replaced by a newer one.