The physical Titanium card can be locked just like other bank cards, but the virtual card cannot.
Lock or unlock Apple Card - Apple Support
If you are seeing payments charged to your card regularly, then you have a subscription that you need to cancel with that merchant. A subscription is a legal obligation to pay for those charges. You will find that locking a card does not cancel a subscription. To cancel a subscription, first you are required to contact the merchant, and if unsuccessful in cancelling the subscription, it can be disputed as fraudulent with the bank of the issued card. That would be Goldman Sachs for the Apple Card.