"I have run a series of tests today, and found that although I can receive emails, I cannot send them. The addresses tested covered a range of yahoo, hotmail, business, iCloud and private domains. The only exception has been to my wife, whose email address uses the same domain as mine. Our email addresses have an Australian business domain, i.e. ‘.com.au’. This problem applies only to my iPhone 16e. I am able to reply to and originate email on my iPad."
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Issues Sending eMails on an iPhone:
A. Start Here: If you can’t Send eMail on your iPhone or iPad - Apple Support
B. Delete ALL PVNs and Uninstall ALL Security Software:
If you are using a VPN or Security Software, you would delete all of the VPNs, and uninstall all of Security Software (use an uninstaller, if required by the Developer).
C. Add these eMAil Accounts Back:
Remove these eMail addresses, and then add them back. Some domains require an App Password to access three Web portals on a third-party app such as that of Mail. Here is the link from Microsoft: How to get and use App Passwords - Microsoft
D. Don't Use Cellular and WiFi Coincidingly:
If using Cellular, toggle off WiFi, and vice verse.