"an app" is just a pretty Macintosh cover on one (or more) normal unix processes. You can use 'ps' to see what processes are running and read the 'nice' manpage to learn how to alter a process's priority. This setting, as controlled by the 'nice' command, applies to a process that is already running (or, with difficulty, at the moment it begins). There are ways to have a program automatically lower its own priority, but you'd need to have access to the source code for said program, which you don't have.