I've just installed 10.6.6 and I get an unknown error (100) when trying to download any app from the Mac App Store. I see no messages in the console. Anyone else getting this?
It should also be noted that you might experience another error dialogue.... that might appear as a blank dialogue but does provide a "retry" button. Once you click on "retry" then you should be good to go.
I found that this error occurred when trying to purchase Aperture via the new App Store. I had previously downloaded the trial version via the old Apple store and having it and its installed folders on my hard disk prevented the App store from letting me purchase.
So, if you have a trial version, trash it, and trash the related folders in your user Library and also the Aperture project folder (wherever you saved it), typically in the Pictures folder.