It would be hard to believe that the Vizio would not connect at faster "n" speeds, but to test, keep the security off, but change the Radio Mode on the AirPort Express to 802.11b/g compatible.
Open AirPort Utility - Click Manual Setup
Click the Wireless tab
Hold down the option key on your Mac while you click on the Radio Mode setting
Choose 802.11b/g compatible
Update
Test with no security to see if you can connect that way. If you can, it's a question of finding the right security settings now. But, the speed on your network will be less than half of what it was before.