Have you been here yet?
http://www.apple.com/support/bootcamp/
It has the "Installation Guide", "FAQ", "Manuals", and others that might give you more info. You might read the "BootCamp Setup Guide" for Snow Leopard a few times just to familiarize yourself with it.
Is your 2nd internal HD blank now? Either way you should be able to do it.
Basically, just let Boot Camp/Windows do the partitioning for you. It should walk you through it. If it's an empty HD just let Boot Camp/Windows Erase/Partition and format it for you. You just need to know which partition is which when it comes time to "format" them.
Just make sure you don't accidentally pick your SSD HD by mistake!
It's been a while since I've done it on my computer, sorry.
I had a new empty HD when I did mine. You don't have to worry about messing it up that way. If I remember right I think Boot Camp will partition it first and then it turns it over to Windows to actually "format" it for the NTFS.
On my 1st drive I have the MAC OS on it and on my 2nd HD I have XP (NTSF) on one partition and Mac/Windows (storage {HFS+}) on the other. I have a Mac Pro tho.
Hope this helps....