I can tell you nothing about a laptop as I don't see a way of measuring what it's using while asleep. As for the desktop you are pretty much spot on, You can use it for about 11 times longer than a 100W light bulb for the same money.
In fact by using one of those price comparison websites I work out that it'd cost, (@ 10.17p/KWH), [24x365] x 0.009 x 0.1017 = £8.018 if it was left on standby all the time for a full year.
That excludes things like a standing charge for the electricity, and assumes you were on the Fixed S@ver Dual Fuel plan from EDF Energy.