Yes, you can do this. When you connect your iPad it creates a backup. So when you now connect your new iPad, and once it is set up, make sure you click on the new device name then click on Restore on the Summary page and choose your "old" iPad backup. This will transfer all settings - except keychain - to your new iPad.
Yes, you can sync multiple iDevices with the same iTunes. If you have apps A, B, C downloaded in iTunes you can have, say, A and B on iPad #1 and B and C on iPad #2. Just use the apps tab in iTunes for each device to manually choose which apps you want to sync.
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how to sync 2 ipads
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