It tends to be used by folks engaged in the old-fashioned process of applying ink to paper but not for much else.
You do realize that every printer you buy uses CMYK to print whatever you send from the computer, right? Many have extra colors (6 and more inks total), usually to boost reds and blues that can't be reached with straight CMYK. But otherwise, they all have at least those four basic colors. You can't print RGB.
Using ColorSync or Graphic Converter is an extremely poor way to convert RGB to the CMYK color space. For instance, the Generic CMYK profile supplied with OS X is probably the worst CMKY profile in the world. Very flat and ugly conversions.
ColorSync also doesn't actually convert images to CMYK. You can open a file and apply a CMYK profile. But when you save the file, it's still RGB.
There's also your target device to consider. The color of any printed image is subject to the inks and paper you're using. Using the same printer, uncoated papers will always be dull compared to coated. Gloss will always be more vibrant than satin. Just as RGB is specific to your monitor profile, CMYK is specific to the output device, whether it's a cheap printer for your computer, or a 40" commercial press. You need to have profiles that are built to match the characteristics of that device, on the paper being used, in order to have any hope that the CMYK image you're viewing on your monitor will look anything like that on press, or from your desktop printer.
Stick with Photoshop. Even the basic CMYK spaces it provides, like U. S. Sheetfed Coated v2 (which you wouldn't have to use without ever having purchased Photoshop), is better than nothing. I don't have, or use Graphic Converter, so I don't know how that works as far as converting.