Thank you for replying. I still have some unanswered questions, so I will provide a scenario and try to explain what I want to achieve:
Mac has two users; 'Admin' (administrator account) and 'dave' (normal account). When logged in as Admin, I turn on FileVault via the SysPrefs pane and the Mac asks to be rebooted (so that corestorage can do its thing i.e. unmount the disk and start the encryption etc). The Mac reboots and immediately shows me an icon for the Admin user and asks for the password. I enter the password and the Mac starts and logs in as the Admin user, without showing me the usual login window. I appreciate, from what you say above, that this is different from the 'Automatic login' setting in Accounts, but the net effect is still the same; the Mac logs in as the user who can unlock the disk.
I add 'dave' to the Filevault pref pane. That user can now unlock the encrypted drive on boot and will now be automatically be logged in, and so on with any additional users I create locally on that machine.
What I would like to achieve is as follows (and please bear in mind that these are Macs in a corporate, managed and supported environment where we use PGP WDE and need a workaround until PGP pull their finger out and support 10.7):
The Mac is encrypted initially under the 'Admin' account. A 2nd user generically called 'diskunlock' with some generic but secure password is added to FileVault. The owner of the machine uses the diskunlock account to unlock the machine, they then get the normal login window and they enter their Active Directory username and password and log in as normal.
PS I know I can use the diskutil command to convert the disk to a corestorage volume and encrypt the machine with a master password, but this is not ideal. I would prefer the use the setup above, if possible. It's just the fact that any user who can unlock a FV disk is automatically logged in that I want to change.
PPS - I must say that corestorage is a fantastic new feature and FileVault2 in a non-corporate environment works really well. My wife loves it on her home macbook 🙂