Can Macs even boot from a FAT32 volume?
No. The drive's file format must be HFS+. The partition map is separate from the file format.
Can one choose the partition map in Disk Utility? I cannot find this option.
Yes. You can go through the steps to see how it's done. Just don't hit Apply, or you'll wipe out the drive. You can't do this test on the startup drive, so choose an external or other physical drive.
Open Disk Utility and click on the physical drive icon at the left, not one of the logical drive names. Such as shown next.
After selecting a physical drive, you'll have the Partition tab at the right. Click on that heading. Notice below the graphic for the Volume Scheme, that Options is grayed out. Change the pulldown for the scheme from Current to anything else. Even just one partition again. The Options button will now be enabled. Click that to show the partition map options.
While some fairly recent Macs will still boot to a drive set as Apple Partition Map, Apple strongly recommends against using it. It's being phased out in favor of GUID. The latest Macs are unlikely to boot to a drive set to use Apple Partition Map. When trying to install OS X to such a drive, it will even tell you it can't be installed on the chosen drive. Click Cancel and then close Disk Utility. It will tell you there are unsaved changes. Click Quit so nothing is applied.
If one reformats the
disk and chooses HFS+ in Disk Utility, it will automatically use GPT, so a less experienced user doesn't need to worry about partition maps.
No, it won't. The partition map will not change no matter how many times your format a drive. You must set the proper partition map manually. So in this case, the user must use Disk Utility to first change the partition map from Master Boot Record to GUID, if they plan on using it as a bootable OS X drive. Even if not, it's still very much recommended to change it to GUID.