If you want to transfer contacts with iTunes, follow the following steps:
1. From the Home screen, select Settings.
2. Select Mail, Contacts, Calendars and then scroll down and press Import SIM contacts. This will copy any phone numbers stored on the SIM to the memory of the iPhone.
3. Now connect your iPhone to your PC using a USB cable. If iTunes doesn't automatically open, press Start and select the program from the list.
4. Once iPhone Transfer has opened, press the iPhone icon that appears on the left-hand side of the iTunes window.
5. From the options displayed, click Info And then tick the box next to Sync Address Book and Contacts.
6. Now press Sync at the bottom of the screen and all your iPhone contacts will be copied to your PC.
Also there is a guide for you:
How to Transfer Contacts from iPhone to Computer