Any hope?
It can be done. But the fact that it can be done does not mean to imply that it should be done.
You might have a bit more wireless coverage mixing the older "b/g" AirPort with the newer "n" AirPort that you have, but even if you can manage to get things working....the configuration is quite difficult for most users....there will be a tremendous performance drop on your network.
You will have to use the older WDS settings for this type of setup. WDS operates at "g" wireless speeds only, so you will lose any advantage of having the newer "n" AirPort Extreme.
Worse, the bandwidth on the entire network drops by 50% in this type of setup. The result will be that you will have a "g" wireless network running at half speed.
To get an idea of this type of configuration, you can review Apple's step by step guide:
http://support.apple.com/kb/HT4262
If you decide to use a second newer AirPort Extreme, then you can use the "Extend a wireless network settings" with which you are familiar. This will maintain much faster "n" speeds on the network....and it is much easier and faster to configure than the WDS setup.
As another option that you perhaps had not considered, is to use a pair of Ethernet powerline adapters to send an Ethernet signal over the AC power lines in your home. In other words, you already have the wiring in place....you just need the adapters.
The "best" option in terms of performance is to run an Ethernet cable from one AirPort to another, but I doubt that the construction of your home would permit this easily. So, the adapters might be the next best bet.
Frankly speaking....wireless only connections between routers, even with newer devices is somewhat "iffy". You do not know if it will work until you try it.
Connecting the AirPorts using an Ethernet connection is called a "roaming" network. The advantage of this approach is that you would not have to replace your older AirPort as it will perform up to its full capability when used with an Ethernet connection.
Apple's instructions for a "roaming" network are here:
http://support.apple.com/kb/HT4260
Two "newer" AirPort Extremes are pictured, but the instructions for your "older" AirPort Extreme would be exactly the same.
Post back if you need more informaton....including some cautions on using the Ethernet powerline adapters.