I use my ppc Mini with my 43" Pioneer Elite plasma, different model number but very similar. VGA works fine, no tweaking necessary. But for my setup, the VGA cable was not ideal (couldn't route it the way I wanted to), so I'm using a DVI-hdmi cable. I had to use DisplayConfigX to get the hdmi setup to work properly (no overscan or underscan), if you search this forum you'll find my settings posted. Looks great either way (VGA or hdmi), especially iPhoto slide shows. If you get the settings right, the aspect ratio will be correct (no distortion).
Since you plan on using VGA anyway, it'll probably work fine without tweaking.
HTH, -Ed
edit: just did a search myself, and I couldn't find my old post. Old posts must get cleared out after a while. If anybody wants, I can lookup my DisplayConfigX settings when I'm home, and post them again here.