Doubling up on vocals is a long-standing technique in recording. It has the effect of making them sound more powerful and "smooth". Of you just double a track, it really only boosts the volume. Some singers will actually sing the song (or part of a song) twice, paying close attention to timing and vocal nuances. A good singer will get it almost perfect, but it will never be absolutely a carbon-copy of the original track. When they are put together, the tiny differences make it sound nice. Just copying and pasting creates a too sterile, too mechanical replication for my liking. You can copy and paste, of course, but think about applying a different EQ to the second track, panning them to various degrees, or dragging one track so that they are slightly out of phase (only slightly, mind you--you don't want to stuff the whole song). These techniques can make it sound like a more natural doubling.