I'm afraid the new 3D shelf is rendered at runtime so customizing it would require code injection (which is never the way to go). Apple no longer uses png files for the dock image, you can simple see this when you take a screenshot of your dock (cmd+shift+4 move your mouse over your dock and hit the space key).
So basically dock customization as of 10.8 is no longer possible. More and more we are pushed into a mold but in the beginning Apple told us to be creative and break the mold. I see OS X Mountain Lion as another mile marker on the super highway of lost functions and diminished individuality.
10.8 is a travesty sure, but if others didn’t see the writing on the wall with Lion, then (a) they should have and (b) what an unfortunate shock ML must be! It brings to mind the classic Apple “1984″ ad except we have seen the enemy and it is well you know who it is! That chick needs to chuck that Olympic hammer right through Tim Cook’s glassed in office! Seriously, we have come full circle and it’s dare I say Linux who is actually doing some interesting innovative things these days!
The saddest and most heartbreaking aspect of this current state of affairs is that the venerable Apple spirit of innovation seems to have been crushed under the boot of protecting users from themselves and all that formerly creative and innovative thinking seems to be marshaled into sandboxing, jailed-apps, DRM, and the inbred, not right in the head offspring of OSX + IOS.
IOSX: the Sad, Shackled, Captive, Declawed Lion.
OS X Mountain Lion: The OS that nobody asked for yet all are stuck with.
Most insulting fact that everything about 10.8 reeks of contempt for the user and a patronizing paternalistic “we know what’s best for you” attitude that basically can be summed up thusly: “You are dumb, try not to mess this up”!
In closing, remembering the “good old days” where one had the freedom to customize his desktop (this freedom of course was not directly given by Apple), but one could remedy the lack of customization by using third party applications like candybar and so on. Is it too much to ask for two or 3 lines of code that would allow the user to customize his dock? Like for example, the could add a tick box under System Preferences > Dock > for transparency and another one for custom image. If Apple is too lazy to do it, I'd be more than happy to volunteer to write and add the code myself.