I have 10 Macs, all operational, only one is attached to a network, my "sacrificial" Mac.
ALL are desktop computers.
Out of the 10, the only one with this annoyance is the one with Mountain Lion installed.
I have not experienced this problem personally with any PPC Mac and no Intel Mac with Snow Leopard installed.
The Mac I use on the net does not have this annoyance, it is running Leopard.
In fact, it does not have the Network Settings problem either.
As I have already gathered.... symptoms vary.
The only commonality among these machines that do not have this annoyance is that the machines are not network attached with one exception.
The Snow Leopard machine is only attached "rarely" and does not have the problem.
(sadly, Mountain Lion is anything but debugged and periodic update checks are required)
Snow Leopard has had only two updates, both Java. (which I did not actually require unless network attached)
My Leopard machines have not had an update in years and neither has the installed software.
While they are exceptionally stable.... they are also quite limited due to advancements in software and rapidly becoming unusable on the internet. (Oh Well.... they work wonderfully)
At the absolute minimum I had to update to Snow Leopard and chose Mountain Lion as my best choice for network activities.
As it works out, not my best choice for anything else.
Mountain Lion has turned my Mac Pro into an "idevice" and spends so much background effort in pre-preparing files for web transfer that compared to Snow Leopard it is typically 30% less efficient. (enough that the user requires no benchmarking tools to easily detect a decrease in performance running identical versions of apps)
My "setup" is not what would be defined as typical.
My actual profession is Energy Physics Research and due to this field of study, my file drive must remain physically electrically separated from my system drive if ANY connection to a network is made. (desktop machines with removable drives or external drives is mandatory)
As far as how this affects or pertains to this problem is irrelevant since a system drive with no personal files has the same problem as I have witnessed.
.... and No.... this field of study requires no working knowledge of a computer's operating system software except how to operate it if needed. (computers do not create research, they record it, the exact opposite of what Hollyweird movies would have a person believe.... but I trust you already know that)
Long story short.
I have never experienced this problem with any Desktop Mac except the one with ML installed.
(this evidently does not hold absolutely true for others)
This machine I am using cannot be used as a baseline study for it is somewhat different than my other standalone machines both in hardware and software. (therefore the answer that "no" this machine does not have this problem becomes irrelevant and could be misleading.... all my posts are relevant to a Mac Pro mid 2012 running ML and no other)
Probably don't need to say this.... fully 90% of the internet is a festering heap of dung and those vidiots out there are doing nothing but slowing down those of us trying to accomplish something tangible and beneficial. What I have witnessed typically is rampant theft of intellectual property and serious waste of time.
Next thing I know, my food processor will require an internet connection for activation.
Funny isn't it.... the first home computers were not used for socializing, they were used for what they were designed for.
Pictures
Movies
Music
Documents / typewriters
Calculators
Art
Design / CAD / Research
and not one of these processes required a network...........not any more!