I have a Synology DiskStation DS413 running DSM 4.1-2668 sharing and mounted by Mountain Lion thru 1G switch network. I did a simple test as below, and it works fine.
(My photos in this testing aperture project already point to the same DSM mounted disk.)
1. Copy (rsync -av) local Aperture project to the DSM shared networked disk.
2. Open Aperture, File -> Switch to Library -> choose project on the DSM mounted folder.
3. Press 'N' to use face detection and add names on some pictures.
4. Close project which opened from DSM mounted folder.
5. Rsync -av "DSM aperture project folder" "My MBP local disk (~/Pictures/)"
6. Open Aperture, File -> Switch to Library -> choose project on my local disk (~/Pictures/).
7. Check the face name I just added, and those pictures still have names I just added.
It seems that the Aperture handle the project library based on file level and xml definiation, so that it , perhaps, still works. But I DONOT promise putting Aperture project file on mounted NAS disk has no problem at all, although Apple says that it won't work.
Of course, networked project solution is a little bit slow than local disk when I do the previewing photos and saving project. But if You have a MBP, a iMac and a NAS at your home, putting aperture library and photos in mounted NAS could be great when you want to edit your photos in both MBP and iMac.