It's possible to upgrade the 6400 to OS 9.1.
You currently have OS 8.0 & you can download a free upgrade to OS 8.1 at Apple's site.
The next level is OS 8.5, however, you have to buy an OS 8.5 install CD & you can download a free upgrade to OS 8.6 at Apple's site.
The next level is OS 9.0, however, you have to buy an OS 9.0 install CD & you can download a free upgrade to OS 9.1 at Apple's site. You can go to OS 9.0 directly without installing OS 8.5/6.
Before installing OS 8.1 & higher, you need to reformat your HD from HFS to HFS+.
One source for system CDs is Apple Rescue
http://www.applerescue.com/index_link.htm
A great source of info on the 6400 & 6500 is at The 6400 Zone at
http://www.zone6400.com
Cheers, Tom