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How do I synch Address Book on an iMac using OSX10.7.5 with a new iPhone 5?

How do I synch an iPhone 5 running version 6.1 OS with the ADDRESS BOOK on an iMac running Snow Leopard OSX 10.7.5? If I enter a new contact in my Address Book on either the iPhone or iMac, that new entry does not appear in the other, nor in the iCloud. I am running the latest version of iTunes. I have tried synching by WIFI and by cable and by turning the iCloud storage backup on the iPhone on and off.