Mac Pro uses UEFI and you can't go in.
A dual Xeon is harder, though as the eVGA SR-X and SR-2 showed it is possible. Though there most go for buying cheaper processors and then OC - rather than start with a pair of X5680s @ $1600 each!!
Games love high clocks and don't need 8 or 12 cores.
You can build a nice PC for the cost of one 5680, GPUs extra for sake of it as you can spend $250 to $1200 on 2-3 nVidia GTX 680s.
You cannot easily put 2-3 GTX 680s in Mac Pro and no support for SLI. And there are advantages to some pro apps havng a GPGPU one that requires some 8-pin cables.
The G5 LCS was a mitigated disaster for about 50% of the units - the Quad G5, the 2,7DP. Noise? I could not hear myself think with those G4 MDD 1.25DPs.
My Mac Pro is my space heater.