No. Autosave/Versions must be built into the app itself to use those OS features. It doesn't work just because it's part of the OS. None of the CS6 apps support it, either. The only Adobe apps that do are the latest versions of Photoshop Elements and Premiere Elements. And that's only because the have to in order to be allowed in the App Store. In both cases, Adobe also gives users a preference to turn it off.
What Adobe did do in Photoshop CS6 is add an autosave feature of their own. It saves your work according to whatever time increment you choose. Then if the app crashes, it will try to reopen the saved data when you relaunch the app.