There are RULES when using more than one drive.
If there is a second drive it cannot be GPT.
So put where you want Windows on SATA "zero" port.
Unplug any others.
Reconnect later.
If you are going to move the SSD to optical, you probably lose your SATA3 interface which you don't want and better to put a slow non-SSD there.
This 'rule' was stumbled upon and learned back with Vista in 2006-7 on Mac Pro machines that have up to 4 internal hard drives. There are rules for UEFI and GPT.
People with iMac and SSD plus a 2nd hard drive have to go through all this as well.
Format non-Windows to FAT and MBR for instance (after making a suitable backup clone) or disconnecting the drive.
Shame it is in some user FAQs but the question should be resolved and known and in the support articles as well what to do and why.
CampTune X works well yet Apple still does not acknowledge it or other useful 3rd party tools for assisting in installing Windows on Mac. On some Macs you can use a drive dedicated to Windows only and dispense with partitioning and using BCA and just use Windows 8 DVD to do the whole install and only aferwards download + unpack and run the support software package drivers you need.
If you move Windows from A to B after install, expect to have to boot from the DVD or to see an error as it will be looking for Windows on port 0 and it will be on port 1 for instance.
That generally is the approach and direction I would take.