Well it would help if you gave details rathr than just say "It does not work" and that you "followed cheats guide"
to get photos out of iPhoto you export - see this user tip for details
To access photos in iPhoto from other programs see this user tip
To set you your email accounts if you can not figure it out call your email service tech support
What exactlhy is not working? What error messages do you get?
and in the details try to be percise - Hotmail is a web email service - Outlook is a email client - you state that they are the same
I use hotmail (now outlook)
- they are not
What version of iPhoto do you use? What email client do you have set in iPhoto?